42 1001 Jose L. Jimenez University of Colorado at Boulder CU HR-ToF-AMS PMF Results and Elemental Ratios of Org MCMA_2006 1 1 2006 03 10 2010 08 26 0 TimeStart_UTC 9 1 1 1 1 1 1 1 1 1 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 -9999 TimeStop_UTC TimeStart_LocalMex TimeStop_LocalMex BBOA HOA LOA OOA HCratio OCratio 1 see Aiken et al., ACP, 2009 and Aiken et al., ACP, 2010 18 PI_CONTACT_INFO: Address: University of Colorado at Boulder, CIRES, 216 UCB, Boulder, CO 80309 PLATFORM: MCMA 2006/T0 LOCATION: Aerosol Room, Bldg. 46, T0, IMP, Mexico City, Mexico ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Ambient non-refractory submicron organic aerosol composition. DATA_INFO: PMF Units: ug/m3, Ratio Units: unitless UNCERTAINTY: N/A ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Data Manager: Allison C. Aiken; allison.aiken@gmail.com PROJECT_INFO: Mexico City Metropolitan Area 2006 Field Campaign STIPULATIONS_ON_USE: Use of these data require prior ok from PI. OTHER_COMMENTS: N/A REVISION: R0 R0: Final Data. TimeStart_UTC TimeStop_UTC TimeStart_LocalMex TimeStop_LocalMex BBOA HOA LOA OOA HCratio OCratio 60902.4 61052.4 39302.4 39452.4 2.82 3.22 0.81 4.07 1.66 0.36 61051.7 61201.7 39451.7 39601.7 1.99 3.51 0.57 4.60 1.65 0.37 62100.3 62250.3 40500.3 40650.3 1.87 2.81 0.79 4.90 1.64 0.39 62253.0 62403.0 40653.0 40803.0 2.27 2.87 0.33 4.79 1.63 0.40 63306.4 63456.4 41706.4 41856.4 1.73 2.54 0.67 5.12 1.62 0.41 63456.5 63606.5 41856.5 42006.5 2.53 1.89 0.92 4.55 1.63 0.40 64507.9 64657.9 42907.9 43057.9 2.74 1.41 0.52 4.12 1.62 0.41 64657.4 64807.4 43057.4 43207.4 2.21 1.72 0.48 3.90 1.62 0.40 65701.9 65851.9 44101.9 44251.9 1.71 1.93 0.70 3.97 1.63 0.40 65851.6 66001.6 44251.6 44401.6 2.08 1.66 0.42 4.84 1.60 0.43 66909.2 67059.2 45309.2 45459.2 1.50 1.63 0.58 3.77 1.62 0.41 67058.7 67208.7 45458.7 45608.7 1.19 1.48 0.43 4.14 1.60 0.43 68100.8 68250.8 46500.8 46650.8 1.76 1.44 0.44 3.75 1.61 0.41 68253.2 68403.2 46653.2 46803.2 1.16 1.10 0.59 3.81 1.60 0.43 69303.0 69453.0 47703.0 47853.0 1.97 1.16 0.32 3.74 1.60 0.43 69455.6 69605.6 47855.6 48005.6 1.85 1.07 0.36 3.71 1.60 0.43 70506.8 70656.8 48906.8 49056.8 2.09 1.11 0.26 3.26 1.61 0.42 70658.9 70808.9 49058.9 49208.9 1.02 0.63 0.32 3.08 1.58 0.45 71709.0 71859.0 50109.0 50259.0 1.35 0.69 0.28 2.28 1.61 0.42 71852.1 72002.1 50252.1 50402.1 1.53 0.95 0.16 2.00 1.63 0.39 72904.0 73054.0 51304.0 51454.0 2.58 0.38 0.28 2.42 1.61 0.41 73053.4 73203.4 51453.4 51603.4 3.41 1.05 0.15 2.86 1.63 0.39 74105.7 74255.7 52505.7 52655.7 2.33 1.27 0.00 2.92 1.62 0.41 74254.9 74404.9 52654.9 52804.9 2.36 1.48 0.21 2.87 1.63 0.39 75307.0 75457.0 53707.0 53857.0 2.06 0.26 0.39 3.43 1.58 0.45 75456.2 75606.2 53856.2 54006.2 1.77 0.57 0.34 3.53 1.58 0.45 76508.6 76658.6 54908.6 55058.6 2.09 0.59 0.12 3.23 1.59 0.44 76657.7 76807.7 55057.7 55207.7 1.85 1.07 0.17 3.15 1.61 0.42 77708.2 77858.2 56108.2 56258.2 2.64 1.15 0.22 3.32 1.62 0.41 77851.6 78001.6 56251.6 56401.6 2.20 0.32 0.56 3.36 1.59 0.43 78906.8 79056.8 57306.8 57456.8 3.34 0.93 0.69 4.54 1.61 0.42 79050.7 79200.7 57450.7 57600.7 3.62 0.99 0.74 4.13 1.62 0.40 80107.0 80257.0 58507.0 58657.0 4.37 0.55 0.98 5.22 1.60 0.42 80256.5 80406.5 58656.5 58806.5 4.20 0.54 1.07 5.79 1.60 0.43 81307.9 81457.9 59707.9 59857.9 2.96 0.94 0.71 4.99 1.60 0.43 81452.4 81602.4 59852.4 60002.4 3.01 1.13 0.91 4.55 1.61 0.41 82508.7 82658.7 60908.7 61058.7 3.46 0.89 0.96 3.99 1.62 0.40 82653.2 82803.2 61053.2 61203.2 3.52 2.53 0.41 4.17 1.64 0.38 83701.7 83851.7 62101.7 62251.7 3.49 1.24 0.60 4.07 1.62 0.40 83851.7 84001.7 62251.7 62401.7 3.83 0.76 1.01 4.38 1.62 0.40 84909.8 85059.8 63309.8 63459.8 5.40 0.79 0.64 4.47 1.62 0.40 85052.5 85202.5 63452.5 63602.5 3.10 0.58 0.47 4.17 1.60 0.43 87305.7 87455.7 65705.7 65855.7 1.84 1.74 0.57 1.86 1.68 0.34 87457.9 87607.9 65857.9 66007.9 1.49 1.73 0.21 2.51 1.64 0.38 93307.9 93457.9 71707.9 71857.9 6.40 2.63 0.48 2.82 1.68 0.33 93457.6 93607.6 71857.6 72007.6 7.03 2.70 0.47 2.75 1.68 0.33 94508.9 94658.9 72908.9 73058.9 5.16 3.82 1.13 2.16 1.71 0.29 94658.0 94808.0 73058.0 73208.0 5.04 4.65 0.30 2.39 1.71 0.30 95708.5 95858.5 74108.5 74258.5 4.51 2.76 0.39 3.21 1.67 0.35 95857.6 96007.6 74257.6 74407.6 5.41 2.41 0.78 2.61 1.68 0.33 96901.9 97051.9 75301.9 75451.9 5.00 2.04 0.82 2.61 1.67 0.33 97051.0 97201.0 75451.0 75601.0 4.96 2.07 0.80 2.78 1.67 0.34 98102.3 98252.3 76502.3 76652.3 1.81 4.33 0.14 3.45 1.68 0.34 98251.7 98401.7 76651.7 76801.7 1.84 4.73 0.48 3.41 1.69 0.33 99308.1 99458.1 77708.1 77858.1 1.61 3.95 0.65 2.89 1.69 0.32 99457.0 99607.0 77857.0 78007.0 1.99 2.98 1.16 3.05 1.68 0.33 100500.8 100650.8 78900.8 79050.8 1.98 4.93 0.69 3.56 1.69 0.32 100658.6 100808.6 79058.6 79208.6 1.85 4.05 0.72 3.96 1.67 0.35 101706.8 101856.8 80106.8 80256.8 4.98 5.11 1.21 3.16 1.70 0.30 101856.3 102006.3 80256.3 80406.3 7.12 6.47 0.42 3.02 1.71 0.30 102907.0 103057.0 81307.0 81457.0 3.77 6.96 1.70 3.99 1.71 0.30 103056.5 103206.5 81456.5 81606.5 3.01 5.86 1.20 3.54 1.71 0.30 104104.1 104254.1 82504.1 82654.1 3.26 6.24 1.66 3.15 1.72 0.29 104253.3 104403.3 82653.3 82803.3 3.12 6.31 2.37 3.53 1.72 0.29 105309.1 105459.1 83709.1 83859.1 2.98 12.57 3.10 5.24 1.73 0.27 105450.9 105600.9 83850.9 84000.9 3.70 12.25 3.22 3.82 1.75 0.25 106504.8 106654.8 84904.8 85054.8 3.14 9.51 2.76 4.56 1.73 0.28 106654.7 106804.7 85054.7 85204.7 3.53 9.94 2.07 4.37 1.73 0.28 107704.6 107854.6 86104.6 86254.6 6.26 8.80 2.77 2.70 1.74 0.26 107854.7 108004.7 86254.7 86404.7 7.10 9.10 2.51 2.39 1.74 0.25 108904.6 109054.6 87304.6 87454.6 14.15 10.78 2.87 0.96 1.75 0.24 109054.6 109204.6 87454.6 87604.6 13.82 10.66 2.82 0.79 1.75 0.24 110106.1 110256.1 88506.1 88656.1 4.80 4.99 1.28 3.18 1.70 0.30 110255.9 110405.9 88655.9 88805.9 4.57 4.78 1.13 3.13 1.70 0.31 111304.8 111454.8 89704.8 89854.8 20.01 16.90 1.53 0.00 1.76 0.23 111455.0 111605.0 89855.0 90005.0 19.18 14.87 2.28 0.00 1.76 0.23 112504.3 112654.3 90904.3 91054.3 17.70 8.14 4.48 1.99 1.73 0.26 112654.4 112804.4 91054.4 91204.4 18.35 9.33 3.10 2.30 1.73 0.27 113707.2 113857.2 92107.2 92257.2 17.92 10.91 3.35 2.61 1.73 0.26 113857.5 114007.5 92257.5 92407.5 19.60 12.23 3.17 2.68 1.73 0.26 114903.3 115053.3 93303.3 93453.3 17.19 13.88 3.42 2.13 1.74 0.25 115054.1 115204.1 93454.1 93604.1 18.49 15.43 2.04 2.23 1.74 0.25 116105.6 116255.6 94505.6 94655.6 18.57 11.45 3.99 2.25 1.74 0.26 116255.8 116405.8 94655.8 94805.8 18.05 9.03 3.11 2.06 1.73 0.26 117303.2 117453.2 95703.2 95853.2 18.71 11.28 3.31 1.58 1.74 0.25 117453.5 117603.5 95853.5 96003.5 19.05 10.72 4.18 1.82 1.74 0.25 118504.2 118654.2 96904.2 97054.2 11.58 8.78 3.04 1.48 1.74 0.25 118654.1 118804.1 97054.1 97204.1 11.60 11.02 2.37 1.64 1.75 0.25 119707.1 119857.1 98107.1 98257.1 19.46 18.82 3.97 1.16 1.76 0.23 119857.8 120007.8 98257.8 98407.8 21.27 16.55 4.25 1.73 1.75 0.24 120906.6 121056.6 99306.6 99456.6 28.39 21.82 3.51 0.00 1.76 0.23 121057.6 121207.6 99457.6 99607.6 27.51 20.21 4.65 0.00 1.76 0.23 122104.5 122254.5 100504.5 100654.5 22.52 16.79 1.80 0.00 1.76 0.24 122255.4 122405.4 100655.4 100805.4 20.56 17.86 2.43 0.59 1.76 0.23 123304.8 123454.8 101704.8 101854.8 16.01 22.90 1.90 0.00 1.78 0.21 123454.8 123604.8 101854.8 102004.8 14.76 22.84 3.01 0.00 1.78 0.21 124508.6 124658.6 102908.6 103058.6 19.29 13.89 5.22 0.37 1.76 0.23 124650.2 124800.2 103050.2 103200.2 18.97 17.80 2.38 0.49 1.76 0.23 125703.7 125853.7 104103.7 104253.7 20.33 13.63 2.89 0.44 1.75 0.24 125854.4 126004.4 104254.4 104404.4 20.66 14.22 2.56 0.84 1.75 0.24 126909.5 127059.5 105309.5 105459.5 22.92 17.46 2.19 0.40 1.75 0.24 127051.3 127201.3 105451.3 105601.3 26.59 17.46 2.59 0.54 1.75 0.24 128105.8 128255.8 106505.8 106655.8 28.40 12.78 4.52 0.68 1.74 0.25 128256.7 128406.7 106656.7 106806.7 26.44 11.23 4.66 1.57 1.73 0.26 129304.6 129454.6 107704.6 107854.6 24.71 16.03 2.62 1.40 1.74 0.25 129455.6 129605.6 107855.6 108005.6 26.35 16.08 2.80 0.20 1.75 0.24 130503.3 130653.3 108903.3 109053.3 27.19 14.54 3.98 0.00 1.75 0.24 130653.6 130803.6 109053.6 109203.6 27.78 15.96 4.39 0.00 1.75 0.24 131704.6 131854.6 110104.6 110254.6 27.51 17.58 5.50 0.00 1.75 0.23 131855.6 132005.6 110255.6 110405.6 27.91 18.06 5.05 0.65 1.75 0.24 142509.2 142659.2 120909.2 121059.2 7.16 5.25 2.98 9.12 1.65 0.36 142652.4 142802.4 121052.4 121202.4 8.92 6.29 2.68 9.41 1.66 0.35 143707.7 143857.7 122107.7 122257.7 9.34 5.27 4.35 9.85 1.66 0.35 143858.2 144008.2 122258.2 122408.2 10.44 6.69 3.61 11.07 1.66 0.36 144902.2 145052.2 123302.2 123452.2 7.35 6.38 2.71 14.15 1.63 0.39 145057.3 145207.3 123457.3 123607.3 6.62 6.08 2.49 12.88 1.63 0.39 146106.0 146256.0 124506.0 124656.0 3.96 3.06 2.24 10.24 1.61 0.42 146255.6 146405.6 124655.6 124805.6 3.41 4.35 0.87 11.35 1.60 0.43 147301.5 147451.5 125701.5 125851.5 3.74 3.28 1.43 10.06 1.61 0.43 147452.6 147602.6 125852.6 126002.6 3.55 4.09 1.48 10.30 1.61 0.42 148508.7 148658.7 126908.7 127058.7 2.76 1.93 1.38 6.11 1.62 0.41 148654.8 148804.8 127054.8 127204.8 2.84 2.45 0.47 6.89 1.60 0.43 149706.4 149856.4 128106.4 128256.4 2.20 2.06 0.44 7.18 1.59 0.45 149855.0 150005.0 128255.0 128405.0 2.33 1.61 0.61 6.62 1.59 0.45 150909.3 151059.3 129309.3 129459.3 2.10 1.56 0.56 5.69 1.59 0.44 151058.3 151208.3 129458.3 129608.3 1.73 2.28 0.14 5.89 1.60 0.44 152100.6 152250.6 130500.6 130650.6 2.12 1.18 0.72 6.27 1.58 0.45 152258.8 152408.8 130658.8 130808.8 1.84 1.54 0.19 6.49 1.57 0.47 153307.8 153457.8 131707.8 131857.8 2.45 1.43 0.92 5.85 1.60 0.43 153458.1 153608.1 131858.1 132008.1 2.93 1.53 0.39 6.33 1.59 0.44 154507.9 154657.9 132907.9 133057.9 3.42 1.45 0.72 7.04 1.59 0.44 154658.1 154808.1 133058.1 133208.1 3.81 0.91 0.87 7.05 1.59 0.45 155703.9 155853.9 134103.9 134253.9 3.35 1.71 0.64 8.00 1.59 0.45 155852.9 156002.9 134252.9 134402.9 2.97 2.07 0.43 8.86 1.58 0.46 156908.6 157058.6 135308.6 135458.6 4.04 1.21 1.22 8.95 1.58 0.45 157057.9 157207.9 135457.9 135607.9 3.90 1.47 0.98 9.79 1.58 0.46 158103.2 158253.2 136503.2 136653.2 3.22 1.21 0.81 9.91 1.56 0.48 158252.5 158402.5 136652.5 136802.5 3.38 0.74 1.38 9.03 1.57 0.46 159309.2 159459.2 137709.2 137859.2 3.21 1.59 0.55 10.58 1.56 0.48 159458.4 159608.4 137858.4 138008.4 3.59 1.14 1.39 9.97 1.57 0.46 160506.6 160656.6 138906.6 139056.6 4.37 1.25 1.07 11.78 1.57 0.47 160656.2 160806.2 139056.2 139206.2 4.61 1.14 1.20 11.49 1.57 0.47 161703.5 161853.5 140103.5 140253.5 4.77 0.92 1.02 12.59 1.56 0.48 161853.4 162003.4 140253.4 140403.4 3.96 1.57 0.85 13.17 1.56 0.48 162907.7 163057.7 141307.7 141457.7 4.61 1.10 1.13 12.17 1.56 0.47 163056.3 163206.3 141456.3 141606.3 4.25 0.88 1.34 12.94 1.56 0.48 164101.2 164251.2 142501.2 142651.2 4.10 1.07 1.32 12.43 1.56 0.48 164255.6 164405.6 142655.6 142805.6 4.27 0.53 1.75 11.96 1.56 0.47 166506.9 166656.9 144906.9 145056.9 4.01 1.00 1.38 13.14 1.56 0.48 166656.9 166806.9 145056.9 145206.9 3.64 0.78 1.57 13.02 1.55 0.49 167705.5 167855.5 146105.5 146255.5 4.20 1.36 0.85 12.02 1.56 0.48 167855.7 168005.7 146255.7 146405.7 3.34 0.75 1.37 11.92 1.55 0.49 168901.3 169051.3 147301.3 147451.3 1.46 1.43 0.54 5.52 1.59 0.45 169059.0 169209.0 147459.0 147609.0 1.75 1.01 0.50 5.30 1.58 0.46 170105.2 170255.2 148505.2 148655.2 1.30 1.27 0.30 4.30 1.59 0.45 170254.6 170404.6 148654.6 148804.6 1.25 1.77 0.15 4.47 1.60 0.44 171307.1 171457.1 149707.1 149857.1 1.04 1.28 0.17 4.82 1.57 0.47 171455.4 171605.4 149855.4 150005.4 1.22 1.44 0.38 4.30 1.60 0.44 172650.9 172800.9 151050.9 151200.9 1.18 1.67 0.42 4.47 1.60 0.43 173704.0 173854.0 152104.0 152254.0 1.67 1.55 0.38 4.27 1.61 0.43 173854.9 174004.9 152254.9 152404.9 1.65 1.87 0.42 4.69 1.61 0.42 174906.1 175056.1 153306.1 153456.1 1.40 1.47 0.17 4.64 1.59 0.45 175055.4 175205.4 153455.4 153605.4 1.54 1.15 0.47 4.52 1.59 0.44 176102.7 176252.7 154502.7 154652.7 1.59 1.16 0.43 4.23 1.59 0.44 176251.9 176401.9 154651.9 154801.9 1.34 1.71 0.40 4.43 1.60 0.43 177303.9 177453.9 155703.9 155853.9 1.24 2.42 0.11 4.39 1.62 0.42 177452.6 177602.6 155852.6 156002.6 1.71 2.33 0.59 3.46 1.65 0.38 178505.4 178655.4 156905.4 157055.4 1.42 2.70 0.48 4.86 1.63 0.41 178654.4 178804.4 157054.4 157204.4 1.51 3.01 1.18 4.64 1.65 0.37 179704.9 179854.9 158104.9 158254.9 1.17 4.30 0.72 4.42 1.67 0.36 179853.9 180003.9 158253.9 158403.9 1.56 3.89 0.56 4.11 1.66 0.36 180904.5 181054.5 159304.5 159454.5 2.23 4.51 0.27 3.74 1.68 0.34 181053.6 181203.6 159453.6 159603.6 2.10 4.17 0.75 4.29 1.67 0.35 182104.7 182254.7 160504.7 160654.7 1.88 3.11 0.58 4.66 1.64 0.38 182254.1 182404.1 160654.1 160804.1 1.38 4.54 0.29 4.17 1.67 0.35 183304.7 183454.7 161704.7 161854.7 1.90 3.84 0.37 4.33 1.66 0.37 183453.5 183603.5 161853.5 162003.5 2.10 3.85 0.68 3.61 1.68 0.34 184505.1 184655.1 162905.1 163055.1 1.39 4.35 0.49 4.20 1.67 0.35 184654.7 184804.7 163054.7 163204.7 1.86 4.32 0.63 3.88 1.68 0.34 185705.0 185855.0 164105.0 164255.0 1.54 4.43 0.74 4.45 1.67 0.35 185854.6 186004.6 164254.6 164404.6 1.92 5.78 0.33 4.32 1.69 0.34 186903.4 187053.4 165303.4 165453.4 2.19 3.42 0.73 3.93 1.66 0.36 187052.9 187202.9 165452.9 165602.9 2.15 4.32 0.28 4.43 1.66 0.36 188105.9 188255.9 166505.9 166655.9 1.79 4.08 0.69 4.82 1.66 0.37 188254.9 188404.9 166654.9 166804.9 2.15 4.10 0.73 4.71 1.66 0.36 189303.3 189453.3 167703.3 167853.3 1.91 6.78 1.31 4.14 1.71 0.30 189452.5 189602.5 167852.5 168002.5 2.54 7.97 1.20 4.45 1.71 0.30 190506.9 190656.9 168906.9 169056.9 1.82 5.74 1.12 4.70 1.69 0.33 190656.6 190806.6 169056.6 169206.6 1.91 6.98 0.67 4.88 1.69 0.33 191704.2 191854.2 170104.2 170254.2 1.41 6.91 0.73 4.68 1.70 0.32 191853.9 192003.9 170253.9 170403.9 2.17 6.64 0.47 5.16 1.68 0.34 192909.0 193059.0 171309.0 171459.0 2.36 15.80 0.66 2.01 1.79 0.22 193058.6 193208.6 171458.6 171608.6 1.80 16.14 1.34 2.64 1.78 0.22 194106.0 194256.0 172506.0 172656.0 2.25 5.49 1.54 4.07 1.70 0.31 194255.8 194405.8 172655.8 172805.8 2.78 6.06 1.52 3.32 1.72 0.29 195301.9 195451.9 173701.9 173851.9 2.98 7.23 0.69 3.50 1.72 0.29 195451.6 195601.6 173851.6 174001.6 2.93 5.72 0.82 3.37 1.71 0.31 196508.0 196658.0 174908.0 175058.0 3.25 5.14 5.36 2.40 1.74 0.24 196657.9 196807.9 175057.9 175207.9 2.69 6.05 3.45 2.87 1.73 0.26 197701.2 197851.2 176101.2 176251.2 4.53 8.53 7.56 0.12 1.79 0.18 197851.5 198001.5 176251.5 176401.5 5.92 7.81 7.85 0.00 1.78 0.19 198907.2 199057.2 177307.2 177457.2 13.57 16.83 2.42 3.67 1.74 0.25 199057.8 199207.8 177457.8 177607.8 15.27 14.77 3.05 1.26 1.76 0.24 200106.6 200256.6 178506.6 178656.6 14.09 13.95 3.33 1.71 1.75 0.24 200257.3 200407.3 178657.3 178807.3 15.01 15.94 2.22 2.08 1.75 0.24 201303.9 201453.9 179703.9 179853.9 13.53 15.58 2.51 1.48 1.76 0.23 201454.6 201604.6 179854.6 180004.6 13.71 15.02 2.87 2.02 1.75 0.24 202501.0 202651.0 180901.0 181051.0 10.67 16.90 3.29 1.72 1.77 0.23 202651.1 202801.1 181051.1 181201.1 10.81 17.52 2.65 1.60 1.77 0.23 203702.7 203852.7 182102.7 182252.7 9.03 9.02 2.12 2.02 1.74 0.25 203853.1 204003.1 182253.1 182403.1 8.95 10.62 1.33 2.66 1.74 0.26 204905.5 205055.5 183305.5 183455.5 7.08 10.19 1.69 3.27 1.73 0.27 205055.7 205205.7 183455.7 183605.7 8.14 11.23 1.62 2.33 1.75 0.25 206108.4 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